Equilibria between Monohydroxo and Dihydroxo-bridged Binuclear Ethylenediamine Rhodium(III) Complexes.
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چکیده
منابع مشابه
Synthesis of Binuclear Monohydroxo Bridged Copper(II) Complexes with 1,10-Phenanthroline and 4,4'-Dimethyl-2,2'-Bipyridine
Tow new compound of type [(chelate)2Cu-OH-Cu(chelate)2] X3.nH2O, where chelate=1,10-phenanthroline; X=Cl¯(n=3.5) and chelate=4,4'-dimethyl-2,2'-bipyridine; (n=5) have been synthesized and their properties investigated. The complexes show room temperature magnetic moment order of 1.0 B.M. per copper atom. The X-band ESR spectrum of powdered sample...
متن کاملsynthesis of binuclear monohydroxo bridged copper(ii) complexes with 1,10-phenanthroline and 4,4'-dimethyl-2,2'-bipyridine
tow new compound of type [(chelate)2cu-oh-cu(chelate)2] x3.nh2o, where chelate=1,10-phenanthroline; x=cl¯(n=3.5) and chelate=4,4'-dimethyl-2,2'-bipyridine; (n=5) have been synthesized and their properties investigated. the complexes show room temperature magnetic moment order of 1.0 b.m. per copper atom. the x-band esr spectrum of powdered samples at room temperature shows typical dm=1 transit...
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متن کاملSynthesis and structures of novel 1-methylcytosinato-bridged (ethylenediamine)platinum(II) and platinum(III) dinuclear complexes.
The reaction of [Pt(en)(H(2)O)(2)](2+) with 1 equivalent of 1-methylcytosine at an initial pH of 6 ultimately led to the 1-methylcytosinato-bridged (ethylenediamine)platinum(II) dimer, [(en)Pt(MetCyt-H)(2)Pt(en)](NO(3))(2) (1). The species during the reactions prior to formation of 1 have been investigated by using (195)Pt NMR spectroscopy. From the reaction mixture the [Pt(en)(MetCyt)(2)](NO(3...
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ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1982
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.36a-0313